Mechanisms of Acylal Hydrolysis in Sulfuric Acid Solutions
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چکیده
منابع مشابه
THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS
The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchlori...
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0019-1035/$ see front matter Published by Elsevier doi:10.1016/j.icarus.2011.06.008 ⇑ Corresponding author. Fax: +1 301 286 0440. E-mail address: [email protected] (M.J. Loeffl We report laboratory studies on the 0.8 MeV proton irradiation of ices composed of sulfuric acid (H2SO4), sulfuric acid monohydrate (H2SO4 H2O), and sulfuric acid tetrahydrate (H2SO4 4H2O) between 10 and 180 K. Usin...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1975
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v75-391